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Paul Mitchell, Freeze and Shine Super Spray-07/17/2020
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Hair StylingStructure such as solid, liquid, aerosol etc.
Form: liquidDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 15, 20241888 Century Park East, Suite 1600
Century City CA 90067
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
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The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 000064-17-5 -- 55.0 -- -- -- -- 007732-18-5 -- -- -- -- -- 888888-13-1 -- -- -- -- -- 058748-38-2 -- -- -- -- -- 888888-12-8 -- -- -- -- -- 068917-51-1 -- -- -- -- -- 094349-62-9 -- -- -- -- -- 084649-86-5 -- -- -- -- -- 090045-98-0 -- -- -- -- -- 084604-14-8 -- -- -- -- -- 102783-01-7 -- -- -- -- -- 000081-13-0 -- -- -- -- -- 000124-68-5 -- -- -- -- -- 000000-00-1 -- -- -- -- -- 000122-40-7 -- -- -- -- -- 000100-51-6 -- Xn -- -- -- -- 000120-51-4 -- Xn, N -- -- -- -- 000101-86-0 -- -- -- -- -- 000107-75-5 -- -- -- -- -- 000078-70-6 -- Xi -- -- -- -- 000080-54-6 -- Xn, N -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)SD Alcohol 38B
000064-17-5
200-578-655.0 No H225, H319 P210, P233, P240, P241, P242, P243, P264, P280, P303+P361+P353, P370+P378, P305+P351+P338, P337+P313, P403+P235, P501 No No Water
007732-18-5
231-791-2-- No -- -- -- No No Acrylates/Hydroxyesters Acrylates Copolymer
888888-13-1
---- No -- -- -- No No VA/Crotonates/vinyl neodecanoate copolymer
058748-38-2
---- No -- -- -- No No Bisamino PEG/PPG-41/3 Aminoethyl PG-Propyl Dimethicone
888888-12-8
---- No -- -- -- No No Fucus Vesiculous Extract
068917-51-1
295-780-4-- No -- -- -- No No Aloe Barbadensis leaf juice
094349-62-9
305-181-2-- No -- -- -- No No Chamomile extract
084649-86-5
283-467-5-- No -- -- -- No No Jojoba extract (simmondsia chinensis)
090045-98-0
289-964-3-- No -- -- -- No No Rosemary extract
084604-14-8
283-291-9-- No H226, H304, H315, H317, H319, H371, H411 P210, P260, P308+P311, P331, P362+P364, P370+P378 No No Bis-PEG-12 dimethicone
102783-01-7
---- No -- -- -- No No Panthenol
000081-13-0
201-327-3-- No -- -- -- No No Aminoethylpropanol
000124-68-5
204-709-8-- No H315, H319, H412 -- No No Fragrance(s)/perfume(s)
000000-00-1
---- No -- -- -- No No Amyl Cinnamal
000122-40-7
204-541-5-- No H400, H410 P273, P391, P501 No No Benzyl alcohol
000100-51-6
202-859-9-- No H302, H332 -- No No Benzyl Benzoate
000120-51-4
204-402-9-- No H302, H400, H412 -- No No Hexyl Cinnamal
000101-86-0
202-983-3-- No -- -- -- No No Hydroxycitronellal
000107-75-5
203-518-7-- No H319, H317 -- No No Linalool
000078-70-6
201-134-4-- No H315, H317, H319 P280 No No Butylphenyl Methylpropional
000080-54-6
201-289-8-- No H302, H315, H317, H361, H412 P201, P202, P281, P308+P313, P405, P501 Yes No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H225 : Highly flammable liquid and vapourH226 : Flammable liquid and vapourH302 : Harmful if swallowedH304 : May be fatal if swallowed and enters airwaysH315 : Causes skin irritationH317 : May cause an allergic skin reactionH319 : Causes serious eye irritationH332 : Harmful if inhaledH361 : Suspected of damaging fertility or the unborn childH371 : May cause damage to organsH400 : Very toxic to aquatic lifeH410 : Very toxic to aquatic life with long lasting effectsH411 : Toxic to aquatic life with long lasting effectsH412 : Harmful to aquatic life with long lasting effects
- P201 : Obtain special instructions before useP202 : Do not handle until all safety precautions have been read and understoodP210 : Keep away from heat/sparks/open flames/hot surfacesP233 : Keep container tightly closedP240 : Ground/bond container and receiving equipmentP241 : Use explosion-proof electrical/ventilating/light/…/equipmentP242 : Use only non-sparking toolsP243 : Take precautionary measures against static dischargeP260 : Do not breathe dust/fume/gas/mist/vapours/sprayP264 : Wash … thoroughly after handlingP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP281 : Use personal protective equipment as requiredP331 : Do NOT induce vomitingP391 : Collect spillageP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP308+P313 : If exposed or concerned: Get medical advice/attentionP337+P313 : Get medical advice/attentionP370+P378 : In case of fire: Use … for extinctionP405 : Store locked upP501 : Dispose of contents/container to
- GHS02 : FlammableGHS07 : IrritantGHS08 : Health HazardGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :July 17, 2020 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING2 3 0 -
V.O.C Information
Volatile Organic Compounds %/Wt. With Solvent : 55.0
Measure of Alkalinity/Acidity of substance or preparation where a level of 7 is considered as neutral.
pH Levels7.1-7.5 -
SVHC declaration
Warning: This product contains Substances of Very High Concern (SVHC).
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Warnings
Hazard StatementsDanger. Highly Flammable liquid and vapor. Causes serious eye irritation.Precautionary StatementsGeneralNone.
PreventionKeep away from heat, hot surfaces, sparks, open flames and other ignition sources. No Smoking. Keep container tightly closed. Ground and bonbd container and receiving equipment. Use explosion-proof electrical/ventilating/ lighting equipment. Use non-sparking tools. Take precautions against static discharge. Wash exposed skin areas thoroughly with soap and water after handling. Wear protective gloves/eye protection/face protection.ResponseIF ON SKIN (or hair): Take of immediately all contaminated clothing. Rinse skin with water.
IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.If eye irritation persists: Get medical advice/attention.In case of Fire: use water fog, foam, dry chemical; CO2 to extinguish.StorageStore in a well-ventilated place. Keep cool.DisposalDispose of contents/container to licensed and permitted disposal or recycling facility. -
Acute health effects
From SDS:Hazards IdentificationEmergency OverviewDanger. Highly Flammable liquid and vapor. Causes serious eye irritation.Potential Health EffectsEye Contact: The liquid may produce eye discomfort and is capable of causing temporary impairment of vision and/or transient eye inflammation, ulceration. The vapor is discomforting to the eye. Splashes may cause severe eye irritation, possible corneal burns and eye damage. Moderately irritating to the eyes. Symptoms of overexposure may include redness, itching, irritation and watering.Skin Contact: May be irritating to skin, especially after prolonged contact. The product can cause allergic skin reactions (e.g., rashes, welts, dermatitis) upon prolonged or repeated exposure.Inhalation: Vapors of this product may be moderately irritating to the nose, throat and other tissues of the respiratory system. Symptoms of overexposure can include coughing, wheezing, nasal congestion, and difficulty breathing. Inhalation of concentrated vapors can cause central nervous system depression (e.g., drowsiness, dizziness, headaches, nausea). Odor may give some warning of exposure, but odor fatigue may occur.Ingestion: If product is swallowed, may cause nausea, vomiting and/or diarrhea and central nervous system depression. -
Chronic health effects
From SDS:
The material may accentuate any pre-existing dermatitis condition. Methylparaben contained in very small amounts in this roduct, ma be a mild aller en to some sensitive individuals. -
Carcinogenicity
Not a suspected carcinogen. -
Handling information
Avoid prolonged contact with the product. Avoid breathing vapors of this product. Use in a well-ventilated location (e.g., local exhaust ventilation, fans). After use, wash hands and exposed skin with soap and water. Do not eat, drink or smoke while handlin roduct. Keep this material away from heat, sparks and open flame. Open containers slowly on a stable surface. Keep container closed tightly when not in use. Empty container may contain residual amounts of this product; therefore, empty containers should be handled with care. Store containers in a cool, dry location, away from direct sunlight, other light sources, or sources of intense heat. Store awa from incompatible materials. Open containers slowly on a stable surface. Keep container tightly closed when not in use. Empty containers may contain residual amounts of this product therefore, empty containers should be handled with care. -
Disposal information
Review current local, state and federal laws, codes, statutes and regulations to determine current status and appropriate disposal method for the ingredients. Any disposal practice must be in compliance with local, state, and federal laws and regulations. -
First Aid
Eye Contact: If product gets in the eyes, flush with copious amounts of lukewarm water for at least 15 minutes. Open and close eyelid(s) to ensure thorough irrigation. Seek immediate medical attention. If problem persists, seek immediate medical attention.Skin Contact: If irritation occurs & product is on the skin, rinse thoroughly with lukewarm water, followed by a thorough washing of the affected area with plenty of soap and water. Remove all contaminated clothing, including footwear and wash thoroughly before reuse. If irritation, redness or swelling persists, consult a physician immediately.Inhalation: Remove victim to fresh air at once. If breathing stops, perform artificial respiration. Seek immediate medical attention.Ingestion: If ingested, do not induce vomiting! Contact the nearest Poison Control Center or local emergency number. Provide an estimate of the time at which the material was ingested and the amount of the substance that was swallowed.
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